The from address webmaster@ des not indicate that there is a account with that address on your system. Check the content of a email in the queue with postcat to see how it was send and if it was sent by one of your websites or by a smtp login.
Still email out mail in a short time form 20 to 65mail , the system only four email account, how to solve problem, I had been stopped postfix service.
Check the content of the emails in the queue with e.g. postcat command or with webmin, if it has a similar function and post the full mail headers.
